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selenium tetrafluoride : ウィキペディア英語版
selenium tetrafluoride

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Selenium tetrafluoride (SeF4) is an inorganic compound. It is a colourless liquid that reacts readily with water. It can be used as a fluorinating reagent in organic syntheses (fluorination of alcohols, carboxylic acids or carbonyl compounds) and has advantages over sulfur tetrafluoride in that milder conditions can be employed and it is a liquid rather than a gas.
==Synthesis==
The first reported synthesis of selenium tetrafluoride was by Paul Lebeau in 1907, who treated selenium with fluorine:
:Se + 2 F2 → SeF4
A synthesis involving more easily handled reagents entails the fluorination of selenium dioxide with sulfur tetrafluoride:〔Konrad Seppelt, Dieter Lentz, Gerhard Klöter "Selenium Tetrafluoride, Selenium Difluoride Oxide (Seleninyl Fluoride), and Xenon Bis()"Inorg. Synth, 1987, vol. 24, 27-31. 〕
:SF4 + SeO2 → SeF4 + SO2
An intermediate in this reaction is seleninyl fluoride (SeOF2).
Other methods of preparation include fluorinating elemental selenium with chlorine trifluoride:
:3 Se + 4 ClF3 → 3 SeF4 + 2 Cl2

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